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chemdzz@nwu.edu.cn

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.师资队伍.
  姓名关正辉   性别:男   民族:汉
  部门:有机化学与化学生物学学部 
  籍贯:山西襄汾   职称:教授
  邮箱:guanzhh@nwu.edu.cn   电话:15002932590(H)    
研究方向: 有机合成化学/有机合成方法学/金属催化
简    介
  关正辉(Zheng-Hui Guan),教授,博士生导师。2004年获得兰州大学学士学位,同年被保送为功能有机分子化学国家重点实验室有机化学研究生;2007年受教育部首届“国家建设高水平大学公派研究生项目”资助,被国家留学基金委选派赴美国Rutgers University (新泽西州立大学)留学,并于2009年6月获得兰州大学和美国Rutgers University(新泽西州立大学)联合培养理学博士学位。2009年7月到西北大学化学与材料科学学院参加工作。现已在J. Am. Chem. Soc.,Angew. Chem. Int. Ed., ChemComm,Org. Lett.,Chem. Eur. J.,J. Org. Chem.,GreenChem, Adv. Synth. Catal., Chem. Asian J. 等国际著名期刊上发表SCI论文35篇。目前,主持国家自然科学基金等项目。

  获奖、荣誉:
  1. 2011年全国优秀博士学位论文提名奖。
  2. 2010-2011年度西北大学优秀教师奖。
  3. 2012年陕西省青年科技新星。
  4. 2012年西北大学优秀青年学术骨干。
  5. 2013年陕西省自然科学优秀学术论文一等奖。

  Dr. Zheng-Hui Guan was born in Xiangfen, Shanxi province, graduated from Lanzhou University in 2004, and received his PhD degree in Lanzhou University (P.R. China) and Rutgers University (USA) in 2009. In 2009, he joined the Department of Chemistry & Materials Science at Northwest University. Professor Guan has published 35 research papers. His research interests currently focus on the development of new synthetic methodologies.

  研究论文(Publications):
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~
  代表性研究成果:
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~

  2014年:

  1. Palladium-Catalyzed Oxidative Coupling of Enamides and Alkynes for Synthesis of Substituted Pyrroles; Mi-Na Zhao, Zhi-Hui Ren, Yao-Yu Wang, and Zheng-Hui Guan*
  Org. Lett. 2014, 16, 608-611.

  2. Copper-Promoted Oxidative Coupling of Enamides and Alkynes for the Synthesis of Substituted Pyrroles; Mi-Na Zhao, Zhi-Hui Ren, Yao-Yu Wang, and Zheng-Hui Guan*
  Chem. Eur. J. 2014, 20, 1839 – 1842.

  3. Copper-Catalyzed Homocoupling of Ketoxime Carboxylates for Synthesis of Symmetrical Pyrroles; Longfei Ran, Zhi-Hui Ren, Yao-Yu Wang, and Zheng-Hui Guan*
  Green Chem. 2014, 16, 112-115.
 
  4. Palladium-Catalyzed Aminocarbonylation of Aryl Iodides with Amides and N-alkyl Anilines; Longfei Ran, Zhi-Hui Ren, Yao-Yu Wang and Zheng-Hui Guan*
  Chemistry-An Asian Journal 2014, 9, 577-583.


  2013年:

  1. Palladium-Catalyzed Oxidative Carbonylation of Alkenyl C−H Bonds of Enamides for Synthesis of 1,3-Oxazin-6-ones;Ming Chen, Zhi-Hui Ren, Yao-Yu Wang, and Zheng-Hui Guan*
  Angew. Chem. Int. Ed., 2013, 52, 14196-14199.
  
  2. Oxidation of 2-arylindoles for synthesis of 2-arylbenzoxazinones with oxone as the sole oxidant;Xiao-Li Lian, Hao Lei, Xue-Jing Quan, Zhi-Hui Ren, Yao-Yu Wang and Zheng-Hui Guan*
  Chem. Commun., 2013, 49, 8196-8198.
  
  3. Copper-Catalyzed Direct Synthesis of Iodoenamides from Ketoximes;Hao Liang, Zhi-Hui Ren, Yao-Yu Wang, and Zheng-Hui Guan*
  Chem. Eur. J. 2013, 19, 9789 – 9794.
  
  4. Cu(TFA)2‑Catalyzed Oxidative Tandem Cyclization/1,2-Alkyl Migration of Enamino Amides for Synthesis of Pyrrolin-4-ones;Zhi-Jing Zhang, Zhi-Hui Ren, Yao-Yu Wang, and Zheng-Hui Guan*
  Org. Lett. 2013, 15, 4822 - 4825.  

  5. Iron-Catalyzed Tandem One-pot Addition and Cyclization of the Blaise Reaction Intermediate and Nitroolefins: Synthesis of Substituted NH Pyrroles from Nitriles;Mi-Na Zhao, Hao Liang, Zhi-Hui Ren, and Zheng-Hui Guan*
  Adv. Synth. Catal. 2013, 355(1), 221-226.
  
  6. FeCl3-catalyzed selfcondensation of enamides for synthesis of enamido substituted nitrogen-containing quaternary carbon centers;Mi-Na Zhao, Wei Du, Zhi-Hui Ren, Yao-Yu Wang and Zheng-Hui Guan*
  Eur. J. Org. Chem. 2013, 7989-7995.

  7. Progress in Transition Metal-Catalyzed Reactions of Oximes and Their Derivatives;Ran Longfei, Liang Hao, and Zheng-Hui Guan* Chin. J. Org. Chem. 2013, 33(1), 66-75.


  2012年:

  1. Palladium-Catalyzed Regioselective Carbonylation of C–H Bonds of N-Alkyl Anilines for Synthesis of Isatoic Anhydrides;Ming Chen, Zhi-Hui Ren, and Zheng-Hui Guan*
  J. Am. Chem. Soc., 2012, 134, 17490-17493.
  
  2. Coupling of enamides with alkynes or arynes for synthesis of substituted pyridines and isoquinolines via amide activation;Mi-Na Zhao, Zhi-Hui Ren, Yao-Yu Wang and Zheng-Hui Guan*
  Chem. Commun., 2012, 48, 8105–8107.
  
  3. Cu(OAc)2/TFA-Promoted Formal [3 + 3] Cycloaddition/Oxidation of Enamines and Enones for Synthesis of Multisubstituted Aromatic Amines;Liang Li, Mi-Na Zhao, Zhi-Hui Ren, Jian-Li Li, and Zheng-Hui Guan*
  Org. Lett. 2012, 14, 3506-3509.
  
  4. Palladium-Catalyzed Carbonylation of Amines: Switchable Approaches to Carbamates and Disubstituted Ureas;Hao Lei, Ming Chen, Zhi-Hui Ren, Yinjuan Bai, Yao-Yu Wang;and Zheng-Hui Guan*
  Adv. Synth. Catal. 2012, 354(2-3), 489-496.
  
  5. Synthesis of Tetrasubstituted NH Pyrroles and Polysubstituted Furans via an Addition and Cyclization Strategy; Li, Liang; Zhao, Mi-Na; Ren, Zhi-Hui; Li, Jianli; Guan, Zheng-Hui*
  Synthesis. 2012, 44, 532-540.
  
  6. Copper-Catalyzed N–N Bond Formation by Homocoupling of Ketoximes via N–O Bond Cleavage: Facile, Mild, and Efficient Synthesis of Azines; Mi-Na Zhao, Hao, Liang, Zhi-Hui Ren, Zheng-Hui Guan*
  Synthesis. 2012, 44, 1501-1506. (Invited Special Topic)
    

  2011年:

  1. Copper-Catalyzed Coupling of Oxime Acetates with Aldehydes: A New Strategy for Synthesis of Pyridines; Zhi-Hui Ren, Zhi-Yuan Zhang, Bing-Qin Yang, Yao-Yu Wang, and Zheng-Hui Guan*
  Org. Lett. 2011, 13, 5394-5397.
  
  2. A Facile and Efficient Synthesis of Multisubstituted Pyrroles from Enaminoesters and Nitroolefins; Liang Li, Zhi-Hui Ren, Jianli Li, Mi-Na Zhao, and Zheng-Hui Guan*
  Green. Chem. 2011, 13, 1664-1668.   
  
  3. Synthesis of Enamides via CuI-Catalyzed Reductive Acylation of Ketoximes with NaHSO3; Zhi-Yuan Zhang, Zhi-Hui Ren, Yao-Yu Wang, Xumu Zhang, and Zheng-Hui Guan*
  J. Org. Chem. 2011, 76, 339-341.  
  

~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ 
  独立工作之前(研究生期间)成果:
~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~ 

  2010年:

  1. Preparation of Indoles via Iron Catalyzed Direct Oxidative Coupling; Zheng-Hui Guan, Ze-Yi Yan, Zhi-Hui Ren, Xue-Yuan Liu, and Yong-Min Liang;
  Chem. Commun., 2010, 46, 2823-2825.

  2009年:

  1. Rhodium-Catalyzed Direct Oxidative Carbonylation of Aromatic C-H Bond with CO and Alcohols; Zheng-Hui Guan,Zhi-Hui Ren,Stephen M.Spinella,Shichao Yu,Yong-Min Liang,and Xumu Zhang;
  J. Am. Chem. Soc. 2009,131,729.

  2. Synthesis of Enamides via Rh/C-Catalyzed Direct Hydroacylation of Ketoximes; Zheng-Hui Guan,Kexuan Huang,Shichao Yu,and Xumu Zhang;
  Org. Lett. 2009,11,481.

  3. Highly Regioselective Synthesis of Benz[a]anthracene Derivatives via aPd-Catalyzed Tandem C-H Activation/Biscyclization Reaction;Zhi-Hui Ren,Zheng-Hui Guan,Yong-Min Liang;
  J. Org. Chem. 2009,74,3145.

  4. Highly Regioselective Hydroformylation of Styrene and Its Derivatives Catalyzed by Rh complexes with Tetraphosphorus Ligands;Shichao Yu,Yu-ming Chie,Zheng-Hui Guan,Yaping Zou,and Xumu Zhang;
  Org. Lett. 2009,11,241.

  5. Suzuki Coupling of Heteroaromatic Chlorides Using Highly Electron-Donating ClickPhos ligands;Stephen M.Spinella,Zheng-Hui Guan,Jian Chen and Xumu Zhang;
  SYNTHESIS 2009,3094.

  6. One-Pot Synthesis of Highly Substituted Aromatic Amine Derivatives via Pd-catalyzed Aminobenzannulation Reaction;Fa-Rong Gou,Peng-Fei Huo,Hai-Peng Bi,Zheng-Hui Guan and Yong-Min Liang;
  Org. Lett. 2009,11,3418.

  7. Palladium-Catalyzed Aryl C-H Bonds Activation/Acetoxylation Utilizing a Bidentate System; Fa-Rong Gou, Xiang-Chuan Wang, Peng-Fei Huo, Hai-Peng Bi, Zheng-Hui Guan, and Yong-Min Liang;
  Org. Lett. 2009,11,5726.

  2008年:

  1. Palladium-catalyzed synthesis of indene derivatives via propargylic carbonates with in situ generated organozinc compounds;Zheng-Hui Guan,Zhi-Hui Ren,Lian-Biao Zhao and Yong-Min Liang;
  Org. Biomol. Chem. 2008,6,1040.

  2. Highly Regioselective Isomerization-Hydroformylation of Internal Olefins to Linear Aldehyde Using Rh Complexes with Tetraphosphorus Ligands;Shichao Yu,Yu-ming Chie,Zheng-Hui Guan,and Xumu Zhang;
  Org. Lett. 2008,10,3469.

  3. New Insight into Ni(II)-Catalyzed Cyclization Reactions of Propargylic Compounds with Soft Nucleophiles:Novel Indenes Formation;Fa-Rong Gou,Hai-Peng Bi,Li-Na Guo,Zheng-Hui Guan,Xue-Yuan Liu,and Yong-Min Liang;
  J. Org. Chem. 2008,73,3837.

  2007年:

  1. An Economical and Convenient Synthesis of Vinyl Sulfones;Zheng-Hui Guan,Wei Zuo,Lian-Biao Zhao,Zhi-Hui Ren,Yong-Min Liang;
  SYNTHESIS 2007,1465.

  2. Copper-Catalyzed[4+1]Cycloadditions of,b-Acetylenic Ketones with Diazoacetates to Form Trisubstituted Furans;Lian-Biao Zhao,Zheng-Hui Guan,Yao Han,Yong-Xin Xie,Sheng He,and Yong-Min Liang;
  J. Org. Chem. 2007,72,10276.

 

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