2017-09-26 08:11:43
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有机化学与化学生物学学部

无机化学与材料化学学部

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书记信箱:
chemdzz@nwu.edu.cn

院长信箱:
chemdir@nwu.edu.cn

 
 
.师资队伍.
  姓名吴彪   性别:男   民族:汉
  部门:无机化学与材料化学学部    出生年月:1971-7
  籍贯:河北   职称:教授
  邮箱:wubiao@nwu.edu.cn   电话:    029-81535020(O)
研究方向: 超分子化学
简    介
本课题组长期招收热爱无机化学、有机化学以及超分子化学的硕士生、博士生和博士后!欢迎对以上领域感兴趣的同学报考加盟!

  学历:

  1988--1992年,兰州大学化学系,本科,学士

  1992--1995年,中国科学院兰州化学物理研究所,硕士,均相催化专业

  1995--1998年,中国科学院福建物质结构研究所,理学博士,物理化学专业。

  工作经历:

  1998-2004年,在德国弗赖堡大学(University of Freiburg)、日本早稻田大学(Waseda University)和美国佐治亚大学(University of Georgia)做博士后研究工作。2004年4-9月,中科院化学所,副研究员。2004年10月-2010年9月,中科院兰州化学物理研究所,研究员,博士生导师。2007年兰州大学兼职教授。2010年10月至今,西北大学化学与材料科学学院,教授,博士生导师。现任西北大学化学与材料科学学院院长。培养的两名博士获得中国科学院朱李月华优秀博士生奖,分别是刘艳艳(2009年),李少光(2011年)。主讲《无机化学与化学分析》课程。

  获奖荣誉:

  享受国务院政府津贴专家;国家“百千万人才工程”入选者;国家“有突出贡献中青年专家”;国家杰出青年科学基金获得者;科技部中青年科技创新领军人才;中国科学院“百人计划”引进海外杰出人才; 陕西省“百人计划”特聘专家;陕西省科学技术奖一等奖(第一完成人)

社会兼职:

陕西省化学会秘书长;中国晶体学会理事;中国化学会理事;西北大学学位委员会委员


  主要研究方向:超分子阴离子化学和超分子催化。

  已发表论文130多篇,其中SCI论文110余篇,包括Angew. Chem. Int. Ed.(5篇), J. Am. Chem. Soc.(1篇), Chem. Commun.(10篇), Chem. Eur. J.(4篇), Inorg. Chem., Org. Lett.等国外著名学术期刊。同时受邀参加国内、国际会议并做学术报告和特邀报告,并发表会议论文30余篇。

  主持国家杰出青年科学基金、国家自然科学基金面上、中国科学院“百人计划”和陕西省重点科技创新团队项目等。

  代表性论文如下,其中*表示通讯作者

[38] J. Zhao, D. Yang, Y. Zhao, L. Cao, Z. Zhang, X.-J. Yang* and Biao Wu*. Phosphate-induced fluorescence of a tetraphenylethene-substituted tripodal tris(urea) receptor. Dalton Trans., 2016, 45, 7360–7365.

[37]L. Ji, Z. Yang, Y. Zhao, M. Sun, L. Cao, X.-J. Yang, Y.-Y. Wang and Biao Wu*. Sandwich phosphate complexes of macrocyclic tris(urea) ligands and their rotation around the anion. Chem. Commun., 2016, 52, 7310-7313.

[36]C. Jia, W. Zuo, D. Zhang, X.-J. Yang and Biao Wu*. Anion recognition by oligo- (thio)urea-based receptors. Chem. Commun., 2016, 52, 9614-9627. (Feature Article)

[35] D. Yang, J. Zhao, Y. Zhao, Y. Lei, L. Cao, X.-J. Yang, M. Davi, N. de Sousa Amadeu, C. Janiak, Z. Zhang, Y.-Y. Wang, and Biao Wu*. Encapsulation of Halocarbons in a Tetrahedral Anion Cage. Angew. Chem. Int. Ed. 2015, 54, 8658–8661.

[34] J. Zhao, D. Yang, Y. Zhao, X.-J. Yang, Y. Wang, and Biao Wu*. Anion Coordination-Induced Turn-On Fluorescence of an Oligourea-functionalized Tetraphenylethene in a Wide Concentration Range. Angew. Chem. Int. Ed. 2014, 53, 632-6636.

  [33]Biao Wu,* F. Cui, Y. Lei, S. Li, N. de Sousa Amadeu, C. Janiak, Y.-J. Lin, L.-H. Weng, Y.-Y. Wang, and X.-J. Yang. Tetrahedral Anion Cage: Self-Assembly of a (PO4)4L4 Complex from a Tris(bisurea) Ligand. Angew. Chem. Int. Ed. 2013, 52, 5096 –5100.

  [32] P. Yang, F. Cui, X.-J. Yang, Biao Wu*. Syntheses and structures of mononuclear, dinuclear and polynuclear silver(I) complexes of 2-pyrazole-substituted 1,10-phenanthroline ligands. Cryst. Growth Des. 2013, 13, 186−194.

  [31] Z. Yang, X. Huang, Q. Zhao, S. Li, Biao Wu*. Hydrogen-bonded 1D nanotubes and 2D layers of group 12 metal complexes with a pyridylurea ligand. CrystEngComm, 2012, 14, 5446–5453.
  [30] Y. Hao, P. Yang, S. Li, X. Huang, X.-J. Yang and Biao Wu*. Selective anion sensing by a ruthenium(II)–bipyridyl-functionalized tripodal tris(urea)receptor. Dalton Trans., 2012, 41, 7689-7694.

  [29] F. Cui, P. Yang, X. Huang, X.-J. Yang, and Biao Wu*. Homometallic silver(I)complexes of a heterotopic NHC-bridged bis-bipyridine Ligand. Organometallics, 2012, 31, 3512-3518.

  [28] M. Wei, Biao Wu*, L. Zhao, H. Zhang, S. Li, Y. Zhao and X.-J.Yang. A bis-bisurea receptor with the R,R-cyclohexane-1,2-diamino spacer for phosphate and sulfate ions. Org. & Biomol. Chem., 2012, 10, 8758-8761.

  [27] S. Li, M. Wei, X. Huang, X.-J. Yang and Biao Wu*. Ion-pair induced self-assembly of molecular barrels with encapsulated tetraalkylammonium cations based on abis–trisurea stave. Chem. Commun. 2012, 48(25), 3097-3099.

  [26] Biao Wu,* C. Jia, X. Wang, S. Li, X. Huang, X.-J. Yang. Chloride coordination by oligoureas: From mononuclear crescents to dinuclear foldamers. Org. Lett. 2012, 14(3), 684-687.

  [25] F. Cui, S. Li, C. Jia, J. S. Mathieson, L. Cronin, X.-J. Yang, and Biao Wu*. Anion-Dependent Formation of Helicates versus Mesocates of Triple-Stranded M2L3(M = Fe2+, Cu2+) Complexes. Inorg. Chem. 2012, 51, 179−187.

  [24] Biao Wu,* J. Yang, X. Huang, S. Li, C. Jia, X.-J. Yang, N. Tang and C. Janiak. Anion binding by metallo-receptors of 5,5'-dicarbamate-2,2'-bipyridine ligands. Dalton Trans.(Cover article) 2011, 40, 5687-569.

  [23] S. Li, C. Jia, Biao Wu,* Q. Luo, X. Huang, Z. Yang, Q.-S. Li*, and X.-J. Yang. A Triple Anion Helicate Assembled from aBis-biurea Ligand and Phosphate Ion. Angew. Chem., Int. Ed. 2011, 50, 5721–5724.

  [22] Z. Yang, Biao Wu,* X. Huang, Y. Liu, S. Li, Y. Xia, C. Jia, and X.-J. Yang. Sulfate encapsulation in a metal-assisted capsule based on a mono-pyridylurea ligand. Chem. Commun. 2011, 47, 2880–2882.

  [21] M. Li, Biao Wu,* C. Jia, X. Huang, Q. Zhao, S. Shao and X.-J.Yang. An Electrochemical and Optical Anion Chemosensor Based on a Tripodal Tris(ferrocenylurea). Chem. Eur. J. 2011, 17, 2272–2280.

  [20] C. Jia, Biao Wu,* S. Li, X. Huang, Q. Zhao, Q.-S. Li* and X.-J.Yang. Highly Efficient Extraction of Sulfate with aTripodal Hexa-urea Receptor. Angew. Chem., Int. Ed. 2011, 50, 486–490.

  [19] Y. Hao, Biao Wu,* S. Li, C. Jia, X. Huang, X.-J. Yang. Coordination polymers derived from a flexible bis(pyridylurea)ligand: conformational change of the ligand and structural diversity of the complexes. CrystEngComm, 2011, 13, 215–222.

  [18] C. Jia, Biao Wu,* S. Li, X. Huang, and X.-J. Yang. Tetraureas versus Triureas in Sulfate Binding. Org. Lett., 2010, 12(24), 5612–5615.

  [17] F. Zhuge, Biao Wu,* L. Dong, J. Yang, C. Janiak, N. Tang, X.-J. Yang. Charge-assisted hydrogen-bonded linear second-sphere assemblies[MΙΙ(DABP)3]3[Cr(C2O4)3]2•14H2O (M = Cu, Ni, Fe, Zn and Mn) with a discrete(H2O)14 cluster of S6 symmetry. Aust. J. Chem., 2010, 63, 1358–1364.

  [16] C. Jia, Biao Wu,* S. Li, Z. Yang, Q. Zhao, J. Liang, Q.-S. Li and X.-J. Yang. A fully complementary, high-affinity receptor for phosphate and sulfate based on an acyclic tris(urea)scaffold. Chem. Commun., 2010, 46, 5376–5378.

  [15] J. Yang, Biao Wu,* F. Zhuge, J. Liang, C. Jia, Y. Wang, N. Tang, X.-J. Yang, and Q.-Z. Shi. Coordination Networks from 0D Metallomacrocycle, Infinite 1D Chains to 2D Network Based on aDitopic Diiminopyridine Ligand and Group 12 Metals. Cryst. Growth Des., 2010, 10, 2331–2341.

  [14] Biao Wu,* J. Yang, Y. Liu, F. Zhuge, N. Tang, X.-J. Yang. Solvent-directed Conformational Variation of Co(II)/(III)Complexes with a Diiminopyridine Ligand. CrystEngComm, 2010, 12, 2755–2761.

  [13] S. Li, Biao Wu,* Y. Hao, Y. Liu, X.-J. Yang. 1D→1D Two-Fold Parallel Interpenetrated Coordination Polymers with a Bis(pyridylurea)Ligand. CrystEngComm, 2010, 12, 2001–2004.

  [12] Biao Wu,* J. Liang, Y. Zhao, M. Li, S. Li, Y. Liu, Y. Zhang, X.-J. Yang. Sulfate encapsulation in three-fold interpenetrated metal-organic frameworks with bis(pyridylurea)ligands. CrystEngComm, 2010, 12, 2129–2134.

  [11] F. Zhuge, Biao Wu,* J. Yang, C. Janiak, N. Tang, and X.-J. Yang. Microscale hexagonal rods of a charge-assisted second-sphere coordination compound[Co(DABP)3][Fe(CN)6]. Chem. Commun. 2010, 46, 1121-1123.

  [10] F. Zhuge, Biao Wu,* J. Liang, J. Yang, Y. Liu, C. Jia, C. Janiak, N. Tang, X.-J. Yang. Full-or half-encapsulation of sulfate anion by a tris(3-pyridylurea)receptor: effect of the secondary coordination sphere. Inorg. Chem. 2009, 48, 10249–10256.

  [9] Z. Long, Biao Wu*, P. Yang, Y. Liu, G. Li, X. Yang. Synthesis and characterization of para-nitro substituted 2,6-bis(phenylimino)pyridyl Fe(II)and Co(II)complexes and their ethylene polymerization properties. J. Organomet. Chem., 2009, 694, 3793–3799.

  [8] Y. Xia, Biao Wu,* Y. Liu, Z. Yang, X.Huang, L.He, and X.Yang. A flexible bis(pyridyl-carbamate)anion receptor: binding of infinite double-stranded phosphate,[-sulfate-(H2O)2-]n, and hydrogen-bridged helical perchlorate chain. CrystEngComm, 2009, 11, 1849-1856.

  [7] P.Yang, X.Yang, Biao Wu*. Synthesis,structure,and spectroscopic and electrochemical properties of copper(II)and copper(I)complexes with symmetrical and unsymmetrical 2,9-diaryl-1,10-phenanthroline ligands. Eur. J. Inorg. Chem. 2009, 2951-2958.

  [6] Y. Liu, S. Li, X.-J.Yang*, P. Yang, Biao Wu*. Magnesium-Magnesium Bond Stabilized by aDoubly Reduced a-Diimine:Synthesis and Structure of[K(THF)3]2[LMg-MgL](L = [(2,6-iPr2C6H3)NC(Me)]22-). J. Am. Chem. Soc., 2009, 131, 4210-4211.

  [5] J. Liang, Biao Wu*, C.Jia, X.-J.Yang. Metallomacrocycle or helix: Supramolecular isomerism in bis(pyridylurea)metal complexes. CrystEngComm, 2009, 11, 975-977.

  [4] P.Yang, Y.Yang, C.Zhang, X.-J.Yang, H.-M.Hu, Y.Gao, Biao Wu*. Synthesis,structure,and catalytic ethylene oligomerization of nickel(II) and cobalt(II) complexes with symmetrical and unsymmetrical 2,9-diaryl-1,10-phenanthroline ligands. Inorg. Chim. Acta 2009, 362, 89-96.

  [3] Y.Yang, P.Yang, C.Zhang, G.Li, X.-J.Yang, Biao Wu*, C.Janiak. Synthesis, structure, and catalytic ethylene oligomerization of nickel complexes bearing 2-pyrazolyl substituted 1,10-phenanthroline ligands. J. Mol. Catal. A: Chem. 2008, 296, 9-17.

  [2]Biao Wu,* J.Liang, J.Yang, C.Jia, X.-J.Yang, H.Zhang, N.Tang, C.Janiak. Sulfate ion encapsulation in caged supramolecular structures assembled by second-sphere coordination. Chem. Commun. 2008, 1762-1764.

  [1] Biao Wu*, X.Huang, Y.Xia, X.Yang, C.Janiak. Oxo-anion binding by protonated(dimethylphenyl)(pyridyl)ureas. CrystEngComm, 2007, 9, 676-685.

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化学与材料科学学院 地址:陕西省西安郭杜教育产业园区学府大道1号 电话:029-81535026 邮件:chembgs@nwu.edu.cn