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有机化学与化学生物学学部

无机化学与材料化学学部

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书记信箱:
chemdzz@nwu.edu.cn

院长信箱:
chemdir@nwu.edu.cn

 
 
.师资队伍.
  姓名曹利平   性别:男
  部门:无机化学与材料化学学部 
  职称:教授
  邮箱:chcaoliping@nwu.edu.cn
研究方向: Supramolecular Chemistry, Host-Guest Chemistry, Molecular Machine, Self-assembly System, Stimuli-responsive System, Drug Delivery
简    介
  本组致力于有机-无机超分子化学、主客体化学、功能材料等相关领域的研究,欢迎对本课题组感兴趣的同学报考!同时欢迎本科学生加入科研团队,为读研做前期准备。地址:西安市长安区学府大道1号,西北大学,化学与材料科学学院,710127。办公室:化材院大楼618,实验室620-622。

  教育与职业经历:
2014年-今:教授,博导,西北大学,化学与材料科学学院。 
2011-2014:博士后,美国马里兰大学,化学与生物化学系。
2006-2011:理学博士,华中师范大学,农药与化学生物学教育部重点实验室。
2002-2006:学士,华中师范大学,化学学院。

  研究兴趣:
  基于分子识别的刺激响应超分子体系的建立;新颖大环分子的合成及其功能化应用研究;抗癌药物的靶向传递体系的建立;分子组装体的合成;超分子框架材料的构筑与性质研究、功能探索。主持国家自然科学基金面上项目、陕西省教育厅自然科学基金重点项目和陕西省自然科学基金面上项目。

  代表性科研成果:

独立工作:

10. 李亚雯; 敖宛彤; 金慧琳; 曹利平* 四苯乙烯衍生物与大环主体在主客体相互作用下的聚集诱导发光, 化学进展, 2018, ASAP.(国内权威综述期刊,SCI)

9. Cao, L.*; Wang, P.; Miao, X.; Dong, Y.; Wang, H.; Duan, H.; Yu, Y.; Li, X.; Stang, P. J.* Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages. J. Am. Chem. Soc. 2018, 140, 7005-7011. (SCI, IF = 14.4, 一区top)

8. Li, Y.; Dong, Y.; Miao, X.; Ren, Y.; Zhang, B.; Wang, P.; Yu, Y.; Li, B.; Isaacs, L.; Cao, L.* Shape-Controllable and Fluorescent Supramolecular Organic Frameworks through Aqueous Host–Guest Complexation. Angew. Chem., Int. Ed.,2018,57, 729-733. (SCI, IF = 11.4, 一区top)

7. Yu, Y.; Li, Y.; Wang, X.; Nian, H.; Wang, L.; Zhao, Y.; Li, J.; Yang, X.; Liu, S.*; L. Cao* Cucurbit[10]uril-based [2]Rotaxane: Preparation and Supramolecular Assembly-Induced Fluorescence Enhancement. J. Org. Chem. 2017, 82,5590-5596. (SCI,IF = 4.785, 二区top)

6. Wang, P.; Wu, Y.; Zhao, Y.; Yu, Y.; Zhang, M.*; L. Cao* Crystalline Nanotubular Framework Constructed by Cucurbit[8]uril for Selective CO2 Adsorption. Chem. Commun. 2017, 53, 5503-5506. (SCI,IF=6.567, 一区)

5. Sigwalt, D.; Sekutor, M.; Cao, L.; Zavalij, P. Y.; Hostas, J.; Ajani, H.; Hobza, P.; Mlimaric-Majerski, K.*; Glaser, R.*; Isaacs, L.* Unraveling the Structure-Affinity Relationship between Cucurbit[n]urils (n = 7, 8) and Cationic Diamondoids. J. Am. Chem. Soc. 2017, 139, 3249-3258. (SCI, IF = 13, 一区top)

4. Li, J.; Zhao, Y.; Dong, Y.; Yu, Y.; Cao* L.; Wu, B. Supramolecular Organic Frameworks of Cucurbit[n]uril-Based [2]Pseudorotaxanes in the Crystalline State. CrystEngComm, 2016, 18, 7929-7933.(前封面文章,SCI = 3.80, 二区)

3. Dong, Y.; Cao, L.* Functionalization of Cucurbit[n]uril. Progress in Chemistry,(化学进展) 2016, 28, 1039-1053.(国内权威综述期刊,SCI)

2. Li, J.; Yu, Y.; Luo, L.; Li, Y.; Wang, P.; Cao, L.*; Wu, B. Square [5]Molecular Necklace Formed from Cucurbit[8]uril and Carbazole Derivative. Tetrahedron Lett. 2016, 57, 2306-2310. (SCI, IF = 2.6, 三区)

1. Yu. Y.; Li, J.; Zhang, M.; Cao, L.;* Isaacs, L.* Hydrophobic Monofunctionalized Cucurbit[7]Uril Undergoes Self-Inclusion Complexation and Forms Vesicle-Type Assemblies. Chem. Commun. 2015, 51, 3762-3765. (SCI, IF = 6.7, 一区)

博士后期间工作:

10. Škalamera, Đ.; Cao, L.; Isaacs, L.*; Glaser, R.* Mlinarić-Majerskia, K.* Steric Hindrance To The Syntheses and Stabilities Of 1,5- and 2,6-Naphthalene N-Permethylated Diammonium Salts. Tetrahedron, 2016, 72,1541-1546. (SCI, IF = 2.6, 三区)

9. Cao, L.; Šekutor, M.; Zavalij, P. Y.; Mlinarić-Majerski, K.*; Glaser R.*; Isaacs, L.* Cucurbit[7]uril.Guest Pair with an Attomolar Dissociation Constant. Angew. Chem., Int. Ed. 2014, 53, 988-993. (SCI, IF = 13.4, VIP paper and Poster of the frontispiece, 一区top)

8. Cao, L.; Hettiarachchi, G.; Briken, V.*; Isaacs, L.* Cucurbit[7]uril Containers for Targeted Delivery of Oxaliplatin to Cancer Cells. Angew. Chem., Int. Ed. 2013, 52, 12033-12037. (SCI, IF = 13.4, 一区top)

7. Vinciguerra, B.#; Cao, L.# (共同第一作者); Cannon, J. R.; Zavalij, P. Y.; Fenselau, C.; Isaacs, L.* Synthesis and Self-Assembly Processes of Monofunctionalized Cucurbit[7]uril. J. Am. Chem. Soc. 2012, 134, 13133-12140. (SCI, IF = 11.4, 一区top) (Spotlights on Recent JACS Publications, J. Am. Chem. Soc. 2012, 134, 14265-14266.)

6. Zhang, M.#; Cao, L.# (共同第一作者); Isaacs, L.* Cucurbit[6]Uril-Cucurbit[7]Uril Heterodimer Promotes Controlled Self-Assembly Of Supramolecular Networks And Supramolecular Micelles By Self-Sorting Of Amphiphilic Guests. Chem. Commun. 2014, 50, 14756-14759. (SCI, IF = 6.7, 一区)

5. Cao, L.; Isaacs, L.* Daisy Chain Assembly Formed from a Cucurbit[6]uril Derivative. Org. Lett. 2012, 14, 3072-3075. (SCI, IF = 6.3, 一区)

4. Cao, L.; Skalamera, D.; Zavalij, P. Y.; Hobza, P.*; Mlinarić-Majerski, K.*; Glaser R.*; Isaacs, L.* Influence of Hydrophobic Residues on the Binding of CB[7] toward Diammonium Ions of Common Ammonium•••ammonium Distance. Org. Biomol. Chem. 2015, 13, 6249-6254. (SCI, IF = 3.5)

3. Cao, L.; Isaacs,L.* Absolute and Relative Binding Affinity of Cucurbit[7]uril Towards A Series of Cationic Guests. Supramol. Chem. 2014, 26, 251-258. (SCI, IF = 2.1)

2. Lucas, D.; Minami, T.; Iannuzzi, G.; Cao, L.; Wittenberg, J. B.; Anzenbacher, Jr. P.*; Isaacs, L.* Templated Synthesis of Glycoluril Hexamer and Monofunctionalized Cucurbit[6]uril Derivatives. J. Am. Chem. Soc. 2012, 134, 13133-12140. (SCI, IF = 11.4)

1. Šekutor, M.; Molčanov, K.; Cao, L.; Isaacs, L.*; Glaser R.*; Mlinarić-Majerski, K.* Design, Synthesis, and X-ray Structural Analyses of Diamantane Diammonium Salts: Guests for Cucurbit[n]uril (CB[n]) Hosts. Eur. J. Org. Chem. 2014, 12, 2533-2542. (SCI, IF = 3.2)

博士期间工作:

19. Cao, L.; Wang, J. G.; Ding, J. Y.; Wu, A. X.*; Isaacs,L.* Reassembly Self-Sorting Triggered by Heterodimerization. Chem. Commun. 2011, 47, 8548-8550. (SCI, IF = 6.7, 一区)

18. Cao, L.; Meng, X. G.; Ding, J. Y.; Chen, Y. F.; Gao, M.; Wu, Y. D.; Li, Y. T.; Wu, A. X.*; Isaacs, L.* Nanotubular Non-Covalent Macrocycle Within Non-Covalent Macrocycle Assembly: (MeOH)(12) Encapsulated in Amolecular Clip Cyclododecamer. Chem. Commun. 2010, 46, 4508-4510. (SCI, IF = 6.7)

17. Cao, L.; Ding, J. Y.; Gao, M.; Wang, Z. H.; Li, J.; Wu, A. X.* Novel and Direct Transformation of Methyl Ketones or Carbinols to Primary Amides by Employing Aqueous Ammonia. Org. Lett. 2009, 11, 3810-3813. (SCI, IF = 6.3) (highlighted by Organic Chemistry Portal: http://www.organic-chemistry.org/abstracts/lit2/649.shtm; ChemInform, 2010, 41, DOI:10.1002/chin.201004082)

16. Cao, L.; Ding, J. Y.; Wang, J. G.; Chen, Y.; Gao, M.; Xue, W. J.; Wu, A. X.* Colorimetric Fluoride Sensor Based on a Bisthiourea Functionalized Molecular Clip. Synlett 2010, 2553-2556. (SCI, IF = 2.8)

15. Cao, L.; Ding, J. Y.; Yin, G. D.; Gao, M.; Li, Y. T.; Wu, A. X.* Thioglycoluril as a Novel Organocatalyst: Rapid and Efficient alpha-Monobromination of 1,3-Dicarbonyl Compounds. Synlett. 2009, 1445-1448. (SCI, IF = 2.8)

14. 曹利平; 高蒙; 李义涛; 丁娇阳; 吴彦东; 祝艳平; 佘能芳; 吴安心* 二元组装体集群时的高选择性杂化重组行为. 中国科学B辑: 化学2009, 39, 343-349. (国家核心期刊)

13. Cao, L.*; Meng, X. G.; Ding, J. Y.; Xi, H. L; Wu, A. X. J. Chem. Crystallogr. 2011, 41, 425-429. (SCI)

12. Cao, L.*; Meng, X. G.; Gao, M.; She, N. F.; Wu, A. X. Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 2008, 64, o69-o72. (SCI3)

11. Zhu, Y.; Yuan, J. J.; Li, Y. T.; Gao, M.; Cao, L.; Ding, J. Y.; Wu, A. X.* Synlett. 2011, 52-56. (SCI)

10. Li, L.;She, N. F.; Fei, Z.; So, P. K.;Wang, Y. Z.; Cao, L.; Wu, A. X.*; Yao, Z. P.* J. Fluorescence 2011, 21, 1103-1110.

9. Ding, J. Y.; Chen, Y.; Wang, J. G.; Wu, A. X.; Cao, L.* J.Chem.Res. 2010, 246-249. (SCI)

8. Gao, M.; Yang, Y.; Wu, Y.-D.; Deng, C.; Cao, L.; Meng, X.-G ; Wu, A. X.* Org. Lett. 2010, 12, 1856-1859.

7. Gao, M.; Yang, Y.; Wu, Y.-D.; Deng, C.; Shu, W. M.; Zhang, D. X.; Cao, L.; She, N. F.; Wu, A. X.* Org. Lett. 2010, 12, 4026-4029.

6. Gao, M.; Cao, L.; Wang, Z. H.; Sun, J. J.; She, N. F.; Wu, A. X.* Synlett. 2009, 315-319. (SCI
5. She, N. F.; Gao, M.; Cao, L.; Wu, A. X.*; Isaacs, L.* Org. Lett. 2009, 11, 2603-2606. (SCI)

4. Wang, Z.; Yin, G.; Qin, J.; Gao, M.; Cao, L.; Wu, A. X. Synthesis 2008, 3675-3681.

3. Li, Y. T.; Meng, X. G.; Cao, L.; Wang, Y. Z.; Yin, G. D.; Gao, M.; Wen, L. L.; Wu, A. X.* Crystal Growth & Design 2008, 8, 1645-1653. (SCI)

2. Zhou, B. H.; Cao, L.; Yin, G. D.; Gao, M.; Wu, A. X.* Can. J. Chem. 2007, 85, 586-591. (SCI)

1. She, N. F.; Gao, M.; Cao, L.; Yin, G. D.; Wu, A. X.* Synlett. 2007, 2533-2536. (SCI)

会议论文
8. Cao, L.* 葫芦脲官能团功能化及其应用. the 15th National Conference on Macrocyclic Chemistry&the 7th National Conference on Supramolecualr Chemistry, 2016.(邀请报告)

7. Yu, Y.; Dong, Y.; Cao, L.* Monofunctionalized Cucurbit[7]uril.the 10th International Symposium on Macrocyclic and Supramolecualr Chemistry,2015,A-20.

6. Cao, L.* 基于葫芦脲大环的金属有机框架.中西部地区无机化学化工学术研讨会, 三峡大学, 宜昌, 2016, p42.

5. Yu, Y.; Li, J.; Cao, L.* Amphiphilic supramolecular assemblies based on monofunctionalized cucurbit[7]uril.The 4th international conference on cucurbituril, 2015, Naikai University, Tianjin, P. R. China.

4. Cao, L.* Synthesis of Monofunctionalized Cucurbit[n]uril. the 17th National Conference on Macrocyclic Chemistry & the 9th National Conference on Supramolecualr Chemistry, 2014, 26.(分会报告)

3. Cao, L.; Isaacs, L.* Monofunctionalized Cucurbit[7]uril.the 9th International Symposium on Macrocyclic and Supramolecualr Chemistry, 2014, A-20.

2. Cao, L.; Isaacs, L.* Synthesis and Daisy-Chain Assembly of Monofunctionalized Cucurbit[6]uril Derivatives. the 8th International Symposium on Macrocyclic and Supramolecualr Chemistry, 2013, A-31.

1. Cao, L.; Ding, J. Y.; Sun, J. J.; Wang, J. G.; Xue, W. J.; Gao, M.; Wu. A. X.* The bimolecular devices based on asymmetric molecular clips. the 15th National Conference on Macrocyclic Chemistry & the 7th National Conference on Supramolecualr Chemistry,2010,256–257.(英国皇家化学会优秀墙报奖)

参与编写专著

1. Cao, L.; Zhao, J.; Yang, D.; Yang, X.-J.; Wu, B.* Hydrogen Bonding-Driven Anion Recognition in Hydrogen Bonded Supramolecular Structures. Springer-Verlag Berlin Herdelberg, 2015, DOI:10.1007/978-3-662-45756-6_5.

专利成果

1. 曹利平*,李亚雯,董运红,《一种用于细胞荧光显色的水溶性荧光染料》,2017, 6.10,中国,申请号:201710434739.7

*通讯作者

  

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